Product ID:UPSIDE DOWN MARKING PAINTS, 03613 SAFETY RED
MSDS Date:07/01/1994
FSC:NIIN:Submitter:N EN
Status Code:A
MSDS Number: CKQRJ

SPRAYON PRODUCTS

31500 SOLON ROAD
SOLON, OH 44139
US

Emergency Phone: 216-292-7400

Info Phone: 800-777-2966

Cage: 09800

SHERWIN-WILLIAMS DIVERSIFIED BRANDS, INC.

BEDFORD HEIGHTS, OH 44146 US

Telephone: 216-292-7400 OR 216-595-8634

Cage: 09800

760 MM HG

CAS: 74-98-6

RTECS: TX2275000

OSHA PEL 1800 MG/M3;1000 PPM

760 MM HG

CAS: 75-28-5

RTECS: TI4300000

127 MM HG

CAS: 110-54-3

RTECS: MN9275000

OSHA PEL 1800 MG/M3;500 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

5.9 MM HG

CAS: 1330-20-7

RTECS: ZE2100000

ACGIH TLV: 434 MG/M3;100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

NAPHTHA (PETROLEUM), HYDROTREATED HEAVY; (V.M.&P. NAPHTHA)

CAS: 64742-48-9

180 MM HG

CAS: 67-64-1

RTECS: AL3150000

OSHA PEL 2400 MG/M3;1000 PPM

ACGIH TLV: 1780 MG/M3;750 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CALCIUM CARBONATE

CAS: 471-34-1

RTECS: FF9335000

BARIUM SULFATE

CAS: 7727-43-7

RTECS: CR0600000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
CNTCT, DEPENDING ON CNDTNS OF USE. TO MINIMIZE EXPOS, FOLLOW RECOMS
FOR PROPER USE, VENT & PPE. ACUTE: IRRIT OF EYES, SKIN & RESP
SYSTEM. MAY CAUSE NERVOUS SYSTEM D EPRESS. EXTREME OVEREXP MAY
RESULT IN UNCON & POSSIBLY DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD
ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPS/SPRAY MISTS. REDNESS
& ITCHING OR BURNING SENSATION MAY IND ICATE EYE OR EXCESSIVE SKIN
EXPOSURE. CHRONIC: PRLNGD & RPTD EXPOSURE TO HEXANE MAY CAUSE
DAMAGE TO NERVE TISSUE OF THE ARMS & LEGS (PERIPHERAL NEUROPATHY),
RESULTING IN MUSCULAR WEAK & LOSS OF SENSAT ION. THIS EFFECT (EFTS
OF OVEREXP)
Effects of Overexposure:HLTH HAZS: MAY BE INCREASED BY THE PRESENCE OF
METHYL ETHYL KETONE. PRLNGD OVEREXP TO SOLVENT INGREDS LISTED MAY
CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY, BLOOD-FORMING,
CARDIOVASCULAR & REPRODUCTI VE SYSTEMS. REPORTS HAVE ASSOC RPTD &
PRLNGD OVEREXP TO SOLVENTS W/PERM BRAIN & NERVOUS SYSTEM DAMAGE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP
AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE.
EYES: FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION. INGEST: NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. GIVE
SEVERAL GLASSES OF WA TER. SEEK MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:<-17.8C, 0.F
Lower Limits:0.7%
Upper Limits:12.8%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG
NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS
TO PREVENT PRESSUR E BUILD-UP & POSSIBLE AUTOIGNITION OR EXPLOSION
WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT. RED LABEL -
EXTREMELY FLAMABLE, FLASH BELOW 21F.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.

Handling and Storage Precautions:NFPA CODE 30B - LEVEL 2 AEROSOLS.
CONTENTS ARE EXTREMELY FLAMABLE. KEEP AWAY FROM HEAT, SPARKS & OPEN
FLAME. VAPS WILL ACCUM READILY & MAY IGNITE EXPLOSIVELY. DURING USE
& UNTIL ALL VAPS ARE GONE: KEE P AREA VENTD - DO NOT SMOKE -
EXTINGUISH ALL FLAMES, PILOT LIGHTS & HEATERS - TURN OFF (SUPDAT)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONCENTRATING & INHALING
CONTENTS CAN BE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG
VAP & SPRAY MIST. AVOID CNTCT W/SKIN & EYES. WASH HANDS AFTER
USING. THIS COATING MAY CNTN MATLS CLASSIFIED AS NUISANCE
PARTICULATES (LISTED "AS DUST" IN INGRED SECTION) WHICH MAY (O THER
INFO)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENT, WEAR PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESP APPRVD BY NIOSH FOR PROT AGAINS MATLS LISTED
IN INGRED SECTION. WHEN SANDIN G OR ABRADING DRIED FILM, WEAR
DUST/MIST RESP APPRVD BY NIOSH FOR DUST WHICH MAY BE GENERATED FROM
THIS PROD, UNDERLYING PAINT OR ABRASIVE.
Ventilation:LOC EXHST PREFERABLE. GEN EXHST ACCEPTABLE IF EXPOS TO
MATLS LISTED IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA
STDS 1910.94, 1910.107, 1910.108.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EMERGENCY EYE WASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Supplemental Safety and Health
HNDLG/STOR PRECS: STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES
OF IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS.
CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN OR EXPOSE TO TEMP
ABOVE 120F. HEAT FROM SUNLIGHT, RADIATORS, STOVES, HOT WATER &
OTHER HEAT SOURCES COULD CAUSE CNTNR TO (OTHER INFO)

Boiling Pt:<-17.8C, 0.F
B.P. Text:<0-395F
Vapor Pres:SEE INGREDS
Vapor Density:HVR/AIR
Volatile Org Content %:65
Evaporation Rate & Reference:FASTER THAN ETHER
Percent Volatiles by Volume:>75

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METAL LISTED IN INGREDIENT SECTION.

Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
DEFINED UNDER THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40
CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE THE
APPLICABLE EPA HAZARDOUS WASTE NUMBER. DO NOT INCINERATE.
DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STAT
E AND LOCAL REGULATIONS REGARDING POLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:DOMESTIC OTHER THAN AIR (DOT): SHIPPING NAME:
INITIATING EXPLOSIVE; HAZARD CLASS: CLASS A EXPLOSIVE; UN/NA
NUMBER: UN0129; DOT LABEL(S): EXPLOSIVE A; SPECIAL INFORMATION:
COLLOIDAL LEAD AZIDE - DOT-E 2462; DOT PLACARD: EXPLOSIVES A.
INTERNATIONAL WATER OR AIR (IMO/ICAO): SHIPPING NAME: IMO: LEAD
AZIDE; HAZARD CLASS: 1.1A; UN NUMBER: 0129; IMO/CIAO LABEL:
EXPLOSIVE; SPECIAL INFORMATION: IATA/ICAO; LEAD AZIDE, WETTED,
FORBIDDEN.

SARA Title III Information:INGREDIENTS SUBJECT TO THE REPORTING
REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT
(SARA) SECTION 313, 40 CFR 372.65 C: XYLENE, ACETONE, BARIUM
SULFATE.
Federal Regulatory Information:THIS MSDS CONFORMS TO THE HAZARD
COMMUNICATION STANDARD 29 CFR 1910.1200(G)(4), FOR SIILAR COMPLEX
MIXTURES. HMIS RATINGS (HEATLH-2; FLAMABILITY-4; REACTIVITY-0).
State Regulatory Information:SEVERAL OF THESE PRODUCTS CONTAIN A
CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH
DEFECTS OR OTHER REPRODUCTIVE HARM.